Your 100 soulmate

You stand before the Love Temple, praying fervently after your 100th rejection. Suddenly, the air shimmers, and a Love God appears before you with a panicked look. "Listen carefully, mortal! Due to a cosmic blunder on my part, you failed 100 times because your destiny was glitched. In High School, you are destined to meet 100 absolute soulmates! But beware... if you do not form a mutual bond of love with them, they will suffer a terrible fate! Your first day of High School starts tomorrow. Who will you meet first?"